Assessing the environmental impacts of three different types of accommodations in Portugal and Spain by using an LCA approach.

The tourism industry, affected by COVID-19, must reduce greenhouse gas emissions. This study evaluated the environmental impact of three hotels in coastal and mountainous regions of Spain and Portugal using Life Cycle Assessment (LCA). Data was gathered via surveys in the Greentour tool. Results indicate that the 2-star hotel (focused on cultural-urban tourism) has the highest impacts in most categories, except for CC, FRD, and POF indicators. The 3-star hotel (beach tourism) contributes the most to CC and FRD indicators, while the hostel (nature-religious tourism) has the highest value in the POF indicator. LCA findings reveal that diesel consumption in the hostel and electricity usage in both the 2-star and 3-star hotels are major contributors to environmental impacts across various categories. Overall, evidence suggests that fossil fuel and electricity usage significantly affect tourism activities environmentally. Interestingly, this study highlights that a 2-star hotel can have a higher carbon footprint (CC indicator) compared to a 3-star hotel, challenging the notion that higher star ratings imply lower environmental impact.

Comparative assessment of two circularity indicators for the case of reusable versus single-use secondary packages for fresh foods in Spain.

Sustainable packaging is a crucial focus in the context of circular economy efforts. This study evaluates the circularity of two secondary packaging systems used in Spanish fresh food produces: Reusable Plastic Crates and Single-use Cardboard Boxes. A Mass Flow Analysis was performed to assess the material flows in the production and use phases of both systems and two circular indicators were applied: the Material Circularity Indicator and Product Circular Indicator. While most previous studies for single-use packaging use these indicators at the product level, this study applies a system approach since the Reusable Plastic Crates can be reused 100 times. The functional unit was defined as the distribution of 1000 tonnes of fresh products, resulting in the distribution of 6,666,700 packages with 15 kg of products. The Material Circularity Indicator and Product Circular Indicator results show that Reusable Plastic Crates are more circular than Single-use Cardboard Boxes. The Product Circular Indicator provides a more comprehensive assessment of circularity by considering multiple life cycle stages, efficiency, and unrecoverable waste, resulting in a difference in circularity evaluations. The indicators used have limitations as they do not consider the resource stock. Further research is needed to explore this aspect.

'Small-scale' tourism versus traditional tourism: Which will be the new key to achieve the desired sustainable tourism?

The tourism sector after COVID-19 has raised different concerns that have lead to a development towards a more sustainable model of tourism. After the health crisis, the increase in environmental awareness of tourists has become evident. In this context, the great paradigm of 'small-scale' tourism has been developed as opposed to traditional tourism. The present work seeks to contribute to sustainable development in the Spanish tourism sector, comparing a hostel in Cantabria (considered as 'small scale' /religious tourism) and a hotel in Lloret de Mar (considered as a traditional tourism) one using the Life Cycle Assessment (LCA) methodology to verify advantages and disadvantages of both types of tourism. The functional unit (FU) used was 'per guest night with breakfast included'. The results have revealed similar results for both establishments in all impact categories, as can be seen in its contribution to Climate Change (4.41 kg CO2 eq./FU caused by the hotel and 4.78 kg CO2 eq./FU by the hostel). The electricity consumption and the impact of the breakfast in the hostel were identified as main contributors to environmental burdens (with 76.72 % of the hotel's impact to climate change and 77.36 % for the hostel); hence, improvement opportunities envisaged were focused on these critical points. On the one hand, a biomass boiler, a solar water-heating system and a hybrid solar/biomass heating are considered a more sustainable alternatives related to electricity. Natural gas and diesel Consumption, respectively. On the other hand, oatmeal, Greek yoghurt and berries are good options for a breakfast with a reduced environmental impact. It is also important to implement responsible and green practices in order to achieve more environmentally sustainable alternative and traditional accommodations. Therefore, it can be concluded by stating that LCA is a tool capable of identifying and studying the processes with the highest environmental impact in order to find out the most sustainable form of tourism.

Extraction of Bioactive Compounds from Spent Coffee Grounds Using Ethanol and Acetone Aqueous Solutions.

Given global coffee consumption, substantial quantities of spent coffee grounds (SCGs) are generated annually as a by-product of brewing coffee. SCG, although rich in bioactive compounds, is nowadays disposed of. The objective of this study is to compare, for the first time and from the same SCG, the efficiency of ethanol-water mixtures and acetone-water mixtures for the recovery of total polyphenols, chlorogenic acid, and caffeine. Acetone at 20% (m/m) was the most convenient solvent to extract all three bioactive compounds simultaneously, yielding 4.37 mg of GAE/g SCG for total polyphenols, chlorogenic acid (0.832 mg 5-CQA/g SCG), and caffeine (1.47 mg/g SCG). Additionally, this study aims to address some challenges associated with the industrial-scale utilization of SCG as a raw material, encompassing factors such as pre-treatment conditions (natural drying and oven drying), storage duration, and the kinetics of the extraction process. No significant difference was observed between the natural drying and oven drying of SCG. In terms of storage duration, it is advisable to process the SCG within less than 3-4 months of storage time. A significant decline of 82% and 70% in chlorogenic acid (5-CQA) and caffeine contents, respectively, was observed after eight months of storage. Furthermore, the kinetic study for the recovery of total polyphenols revealed that the optimal extraction times were 10 min for acetone at 20% and 40 min for water, with a yield increase of 28% and 34%, respectively. What is remarkable from the present study is the approach considered, using the simplest operating conditions (minimal time and solvent-to-solid ratio, and ambient temperature); hence, at an industrial scale, energy and resource consumption and equipment dimensions can be together reduced, leading to a more industrially sustainable extraction process.

Life cycle assessment to address the environmental impacts of tourism in a Spanish tourist destination: The case of Rias Baixas (Galicia) holidays.

Tourism has grown steadily in recent decades, becoming a strategic sector for the economy in many countries. However, the environmental impacts associated with tourism have also experienced an upward trend. In this sense, innovation is needed in the tourism sector, to move towards new models and strategies that integrate environmental sustainability with the social aspects of the sector. In this study, a holistic assessment of the environmental impact of tourism has been carried out using the Life Cycle Assessment (LCA) method, considering all stages of tourism activity: transportation from the place of origin to destination and back, accommodation, catering, and activities conducted. For this purpose, a case study has been carried out based on a typical trip made from Madrid to Rías Baixas (Galicia), considering a four-night stay and the performance of two activities (music festival and cultural museum) at the destination. Two alternative transportation scenarios (train or plane) have been defined to analyze the influence of the type of transportation on the overall impact. Other touristic activities such as visiting gardens or thermal baths instead of visiting a cultural museum or attending a music festival have been analyzed and it has been found that the thermal baths and the museum have the greatest environmental impacts. Transportation was the biggest contributor to most of the environmental impacts in the selected categories. On the other hand, the stay at the destination has stood out due to the impact of the consumption of food and energy used at the accommodation facility. The impact of the activities conducted at the destination is also worth highlighting. Finally, alternative scenarios for transportation have shown that the mode of transportation selected is key for lowering the overall environmental impact of the stay at the destination, highlighting the public transportation alternative, such as the train, as the most environmentally friendly option.

Carbon accounting of negative emissions technologies integrated in the life cycle of spirulina supplements.

Carbon dioxide removal (CDR) technologies are considered essential to accomplish the Paris Agreement targets. Given the important contribution of the food sector to climate change, this study aims to investigate the role of two carbon capture and utilization (CCU) technologies in decarbonizing the production of spirulina, an algae product commonly consumed for its nutritional characteristics. The proposed scenarios considered the replacement of synthetic food-grade CO2 in Arthrospira platensis cultivation (BAU scenario) with CO2 from beer fermentation (BRW) and CO2 from DACC (direct air carbon capture) (SDACC), representing two alternatives with great potential in the short and medium-long term, respectively. The methodology follows the Life Cycle Assessment guidelines, considering a cradle-to-gate scope and a functional unit equivalent to the annual production of spirulina in a Spanish artisanal plant. Results showed a better environmental performance of both CCU scenarios as compared to BAU, reaching a reduction of greenhouse gas (GHG) emissions of 52 % in BRW and of 46 % in SDACC. Although the brewery CCU offers a deeper carbon mitigation of spirulina production, the process cannot reach net zero GHG emissions due to residual burdens across the supply chain. In comparison, the DACC unit could potentially supply both the CO2 needed in spirulina production and work as a CDR to compensate residual emissions, which opens the door for further research on its technical and economic feasibility in the food sector.

Methodological guidelines for the calculation of a Water-Energy-Food nexus index for seafood products.

Indicators from life cycle assessment methodologies (i.e., footprints) have emerged as useful tools for identifying and communicating the environmental impacts of a system thanks to they are accessible and intuitive and easy to understand to non-expert public. However, the focus on a single environmental problem is one of their main drawbacks. From this idea arises the concept of Water-Energy-Food (WEF) nexus, with the aim of raising awareness of the connections between the universal rights to water supply, energy security and food provision. Regarding the latter, the fisheries sector stands out as a fundamental pillar in the fight against malnutrition. In this sense, the European project "blue growth" aims to ensure that the development of the marine sector is not linked to the degradation of its ecosystems. However, although producers and authorities are willing to communicate the sustainability of products, there is still no standard methodology for reporting it. With the purpose of remedying this current situation, this paper aims to provide technical guidance to calculate a single WEF nexus index for ecolabelling seafood products in the European framework (Atlantic area). Therefore, through this, it is expected to create a useful communication channel between producers and consumers through an easy-to-read ecolabel. Nonetheless, certain aspects, such as the footprints selected or the calculation procedures selected have to be reconsidered to refine the methodology proposed, apart from broadening the approach to other food sectors with the aim that the proposed eco-certification can be present in major supply and retail chains.

Environmental and Yield Comparison of Quick Extraction Methods for Caffeine and Chlorogenic Acid from Spent Coffee Grounds.

This study aims to provide an overview of different extraction methods to obtain chlorogenic acid (CA) and caffeine (Caf) from spent coffee grounds (SCG). This overview shows that the quantity extracted is highly dependent on the type of SCG, so experiments using the same SCG are needed to compare different methods. Three easy and simple extraction methods will be tested at a laboratory scale and environmentally compared. All three experiments were of 1 min duration: first, using supramolecular solvent; second, with water and vortex; and third, with water assisted by ultrasound. Water extraction assisted by ultrasound at room temperature yielded the greatest quantity of chlorogenic acid and caffeine, with 1.15 mg CA/g and 0.972 mg Caf/g, respectively. Extraction using supra-solvent leads to a lower content of CA in the supra-phase since it has more affinity for the water-based inferior phase. An environmental assessment using life cycle assessment has been carried out to compare water and supra extraction methods for the manufacture of two different commercial products: a face cream and an eye contour serum. Results show that the type of solvent and the amount of active substance extracted have a great influence on the environmental results. The results presented here are important for companies willing to obtain these active substances at an industrial scale.

Environmental performance of Cantabrian (Northern Spain) pelagic fisheries: Assessment of purse seine and minor art fleets under a life cycle approach.

The perpetuation of fishing activity from an environmentally, socially and economically sustainable approach is essential to guarantee not only the future of coastal populations, but also the supply of high-value seafood for society and the safeguarding of cultural heritage. This article aims to assess the environmental performance associated with fishing fleet operations in Cantabria (northern Spain) under a life cycle thinking from a holistic approach. Thus, the Life Cycle Assessment (LCA) methodology was applied under a 'cradle-to-port' approach, setting the functional unit as 1 kg of fresh fish landed. Inventory data on the main inputs and outputs were collected from a sample of 57 vessels covering for the first time the main techniques, purse seine and minor art fisheries. The results identified that the vessel use stage was the responsible of most of the impacts. In line with the literature, diesel consumption stood as the chief hotspot in six of the seven impact categories analysed. Purse seiners got a value of 0.25 kg of fuel per kg of fish landed, while the performance of the minor art fleet showed significantly lower consumption (0.07). Regarding impacts on climate change, this study found a quantity of 1.00 and 0.34 kg CO2 eq. per FU, for purse seine and minor arts, respectively. These figures were consistent with the expected results for pelagic fisheries. For the remaining indicators, purse seiners generally performed worse. The LCA methodology provided outcomes that allow the proposal of potential improvements and measures to foster the transition towards a more sustainable smart-fishing sector. Further research efforts should focus on the development and implementation of renewable energy and low-carbon vessel propulsion technologies.

Carbon Footprint: The Case of Four Chicken Meat Products Sold on the Spanish Market.

Despite its relatively low environmental impact within the livestock sector, the poultry sector still faces its own environmental challenges that need to be addressed. The present paper uses life cycle assessment to quantify greenhouse gas emissions, from cradle to slaughterhouse gate, of four chicken meat products: whole carcass, wings, breast fillets, and leg quarters. The main contribution of the present study is that it provides a detailed analysis of different chicken meat cuts, testing mass and economic allocation choices and showing that economic allocation better reflects the causality of the cutting process. We recommend that a distinction should be made between whole carcass and meat cuts, as there are significant differences in meat content and climate change results between these two categories. This is not so clear in the literature, nor in the LEAP guideline for the poultry sector. The study was performed by using disaggregated inventory data from Spain, for the first time. Results show that the major contributors to environmental impact are feed production (>70%), electricity use (10.2%), and fossil fuel combustion (8.1%). Packaging did not significantly contribute to the climate change impact of the chicken products evaluated (0.4−3.4% contribution, depending on the type of packaging and product considered).

Climate change mitigation potential of transitioning from open dumpsters in Peru: Evaluation of mitigation strategies in critical dumpsites.

Waste management is a critical policy towards the reduction of environmental impacts to air, soil and water. Many Latin American countries, however, lack a correct waste management system in many cities and rural areas, leading to the accumulation of unmanaged waste in illegal or unregulated dumpsites. The case of Peru is of interest, as it hosts 5 of the 50 largest dumpsites in the world. An erratic waste management compromises climate actions for Peru to commit with the Paris Agreement, as no correct closure systems are established for these dumpsites. Therefore, the main objective of this study is to assess the contribution of the past and present biodegradable waste produced and disposed of in the most critical open dumpsters to the overall annual greenhouse gas (GHG) emissions of Peru using the IPCC model. Thereafter, the climate change mitigation potential of possible dumpsite closure strategies based on a selection of technologies, including economic feasibility, were estimated. Results show that cumulative GHG emissions in 2018 for the 24 critical dumpsites evaluated added up to 704 kt CO2 eq. and a cumulative value of 4.4 Mt CO2 eq. in the period 2019-2028, representing over 40 % of solid waste emissions expected by 2030. Mitigation potentials for these emissions tanged from 91 to 970 kt CO2 eq. in the ten-year period depending on the mitigation strategies adopted. The costs of these strategies are also discussed and are expected to be of utility to complement Peru's waste management commitments in the frame of the Paris Agreement.

Tourism under a life cycle thinking approach: A review of perspectives and new challenges for the tourism sector in the last decades.

Sustainable tourism should be promoted as a new system for the sustainable management of resources from a socioeconomic and environmental point of view. For this purpose, it is necessary to develop a tool capable of assessing the impacts associated with the sector and to identify which actions are currently being addressed in order to achieve the desired sustainability. This timely study aims to describe the current framework of Life Cycle Assessment (LCA) and its application to the tourism sector. To address these questions, a total of 83 documents (77 reviews and 6 international reports) were evaluated, assessing the geographical distribution, the temporal evolution of the publications, as well as the most relevant characteristics of the tourism industry articles were evaluated such as, life cycle inventory (LCI), system boundaries, functional unit (FU), methods, environmental indicators and impact categories considered. The study identifies key recommendations on the progression of LCA in tourism sector. As important results, it stands out that 94 % of articles were from the last decade and 21 % of the articles reviewed cover sustainable tourism term, considering the three dimensions. This review showed that in LCA studies the most common method was CML 2001; the most widely used environmental indicator was the Carbon Footprint (CF) and the Global Warming Potential (GWP) was the impact category used in all the studies. Hence, LCA is a highly effective tool capable of assessing direct and indirect carbon emissions in tourism as well as the socioeconomic and environmental impacts generated in this sector. COVID-19 pandemic is also an object of discussion in the framework of the sustainable tourism together with advocating support for the eco-labelling and digitalisation of the tourism experiences as valuable tools to minimize environmental negativities, to promote mechanisms to access green markets and to frame successful synergies.

Water-Energy-Food Nexus and Life Cycle Thinking: A New Approach to Environmental and Nutritional Assessment of Potato Chips.

The water-energy-food (WEF) nexus has become a key concept to promote the cross-sectoral coordination toward sustainable development. In particular, understanding the interdependences of these pillars, as well as addressing a life cycle perspective, is essential when evaluating food production systems. This study explores the environmental impacts and nutritional quality of potato chips, addressing life cycle thinking and a WEF nexus approach. For this purpose, the combined application of life cycle assessment (LCA) and the Nutrient-Rich Food 9.3 (NRF9.3) index was considered to identify the main environmental hotspots and advanced opportunities. The results indicated a major contribution of the cultivation stage on water use, whereas the processing accounted for most of the impacts in energy-related indicators and eutrophication potentials. Improvement opportunities reside in the joint application of drip irrigation, allowing to achieve important water savings, as well as the use of natural gas or pellets instead of diesel, which constitute cleaner energy sources. On the other hand, a poor nutritional density of potato chips became evident from the quantification of the NRF9.3, which can be significantly improved if potatoes undergo a roasted process instead of frying.

Environmental sustainability of alternative marine propulsion technologies powered by hydrogen - a life cycle assessment approach.

Shipping is a very important source of pollution worldwide. In recent years, numerous actions and measures have been developed trying to reduce the levels of greenhouse gases (GHG) from the marine exhaust emissions in the fight against climate change, boosting the Sustainable Development Goal 13. Following this target, the action of hydrogen as energy vector makes it a suitable alternative to be used as fuel, constituting a very promising energy carrier for energy transition and decarbonization in maritime transport. The objective of this study is to develop an ex-ante environmental evaluation of two promising technologies for vessels propulsion, a H2 Polymeric Electrolytic Membrane Fuel Cell (PEMFC), and a H2 Internal Combustion Engine (ICE), in order to determine their viability and eligibility compared to the traditional one, a diesel ICE. The applied methodology follows the Life Cycle Assessment (LCA) guidelines, considering a functional unit of 1 kWh of energy produced. LCA results reveal that both alternatives have great potential to promote the energy transition, particularly the H2 ICE. However, as technologies readiness level is quite low, it was concluded that the assessment has been conducted at a very early stage, so their sustainability and environmental performance may change as they become more widely developed and deployed, which can be only achieved with political and stakeholder's involvement and collaboration.

The fishing and seafood sector in the time of COVID-19: Considerations for local and global opportunities and responses.

This article provides an overview of the impact of the COVID-19 pandemic on the fishing sector over the world, including several economic, social, environmental, and health challenges that the fisheries have had to face during the early days of the health crisis, and some of them still continue today. These problems, in short, are translated into a decrease in seafood demand, loss of jobs, changes in food consumption habits, economic losses, or increased vulnerability of the industry. As a consequence, governments have been forced to implement regulations and measures in support of this sector. However, a positive aspect of the pandemic also stands out, the opportunity to transform the food system to be greener, more inclusive, and resilient against future shocks.

Potential climate benefits of reusable packaging in food delivery services. A Chinese case study.

In China, the food delivery packaging waste is increasing due to the rapid growth of the sector and the use of single-use packaging to transport the meals. In addition, the recycling rates of current municipal waste management are low. In this regard, this study aims at estimating the climate change impact of current food delivery packaging and its waste treatment, by performing a Life Cycle Assessment with a cradle-to-grave approach. In addition, this article explores the potential benefits of increasing the current recycling rates, the recycled content of the packaging as well as the use of reusable packaging. For this study, the food packaging of a typical dumpling-based meal of the popular Chinese restaurant Xijiade was selected. Based on this menu and the current Chinese consumption patterns, the food delivery packaging in China would have emitted about 13 million tons of CO2eq. Increasing current recycling rates to 35% would reduce 16% the emissions of single-use packaging, and further decrease (60%) could be found if half of the packaging was made of recycled material. In addition, if single-use packaging was replaced by reusable PP-based packaging (food container and carrier bag), the emissions would potentially be 63% lower than the current situation. In this case, doubling the recycling rates and the recycled content of the reusable food packaging would represent an extra 6 and 17% reduction of emissions, respectively.

Towards a Water-Energy-Food (WEF) nexus index: A review of nutrient profile models as a fundamental pillar of food and nutrition security.

The Water-Energy-Food (WEF) nexus approach should be promoted as a tool for sustainable management of resources through the interconnection of these three fundamental pillars. Particularly, food security must ensure healthy and balanced diets for everyone, but selecting individual indicators to assess all slants covered by this element is not an easy task. Hence, the objective of this paper is two-fold, to review nutrient profiling (NP) models that allow to categorize foods and evaluate diets based on their nutritional quality, and to choose the most appropriate model to be used within a WEF nexus index. To address this issue, a total of 159 documents were assessed, appraising the geographic distribution, and time evolution of the publications, as well as the characteristics and potential applications of the NP systems. The review concludes that the NRF9.3. model is the most liable option to be used in a WEF nexus index, presenting the best characteristics by means of the definition of scores and thresholds, and the use of an 'across-the-board' criteria and a reference quantity of 100 kcal, alongside offering higher ability to assess diets and foods than the other competitive model (HEI) through the evaluation of nutrients to encourage instead of foods. A secondary outcome of the review is the identification of the NP models as a useful tool to enable institutions with information to establish policies in the field of public health and facilitating the decision-making process according to the current healthy claims.

Techno-economic and environmental assessment of methane oxidation layer measures through small-scale clean development mechanism - The case of the Seychelles.

Unclosed coastal landfills in small island developing states are major sources of greenhouse gases and other environmental impacts. This is a major problem for sustainable waste management systems mainly due to the lack of economic resources. The clean development mechanism (CDM) appears as a possibility to facilitate sustainable financing. Implementing a methane oxidation layer (MOL) emerges as a feasible technical option for this kind of small landfills since landfill gas extraction is usually not viable. This paper presents a techno-economic and environmental assessment of MOL implementation in the Providence landfill (Seychelles) as a small-scale CDM measure. Results show that the MOL measure could avoid by 2030 between 94 and 20 kt CO2 eq. Concerning profitability, results clearly show that it depends on the existence of stabilized biomass material within the island. Thus, the MOL measure starts to be profitable in some scenarios for certified emission reductions (CER) prices higher than 26 €/t CO2 eq. that seem possible depending on the emissions' market development. When not profitable under CDM, the MOL measure might be used to reduce CO2 emissions from the domestic climate effort under the Paris Agreement since the unitary abatement costs is between 10 and 423 €/t CO2 eq. Moreover, the MOL measure contributes to the sustainable development goals (SDG) achievement - mainly SDG8, SDG13, and SDG14. Finally, results call for a prompt action in Seychelles since the sooner the MOL is implemented after the landfill is closed, the more profitable.

Life cycle assessment of fish and seafood processed products - A review of methodologies and new challenges.

Life cycle assessment (LCA) has been widely applied in many different sectors, but the marine products and seafood segment have received relatively little attention in the past. In recent decades, global fish production experienced sustained growth and peaked at about 179 million tonnes in 2018. Consequently, increased interest in the environmental implications of fishery products along the supply chain, namely from capture to end of life, was recently experienced by society, industry and policy-makers. This timely review aims to describe the current framework of LCA and its application to the seafood sector that mainly focused on fish extraction and processing, but it also encompassed the remaining stages. An excess of 60 studies conducted over the last decade, along with some additional publications, were comprehensively reviewed; these focused on the main LCA methodological choices, including but not limited to, functional unit, system boundaries allocation methods and environmental indicators. The review identifies key recommendations on the progression of LCA for this increasingly important sustaining seafood sector. Specifically, these recommendations include (i) the need for specific indicators for fish-related activities, (ii) the target species and their geographical origin, (iii) knowledge and technology transfer and, (iv) the application and implementation of key recommendations from LCA research that will improve the accuracy of LCA models in this sector. Furthermore, the review comprises a section addressing previous and current challenges of the seafood sector. Wastewater treatment, ghost fishing or climate change, are also the objects of discussion together with advocating support for the water-energy-food nexus as a valuable tool to minimize environmental negativities and to frame successful synergies.